Worried about her reputation, Hime covers shifts for a cafe manager she accidentally injures to maintain her picture-perfect princess image. But this cafe has a peculiar theme—private school. To put on her best barista schoolgirl act, she’ll be trained by the most graceful girl there, Mitsuki. Under her guidance, Hime’s feelings start to brew, but there’s just one problem—Mitsuki can’t stand her!
Shiraki is an angel loved by everyone. However, it's all an act, a façade, a lie to make her absolute dream come true; Marry into wealth!
Hime fails to hide the truth of her new job when Kanoko follows her to work, and the surprises continue when Kanoko interviews to become the newest waitress at Café Liebe.
Hime's quest to win over her Onee-sama continues, until she accidentally lets her secret slip and her façade falls down around her.
Once Mitsuki reveals her real name on her school ID, Hime suddenly remembers an important and painful memory from her past involving someone she used to consider a trusted friend.
Hime and Mitsuki struggle to put their history behind them, but their real feelings bubble up and it starts to affect their café work. Mai, Sumika, and Kanoko try to intervene.
Hime tries to find a way to save Mitsuki and dispel the rumors swirling about them, but discovers the answer is a lot simpler than she thought. Meanwhile, Sumika starts to look a little bit closer at Kanoko.
The café is busier than ever as the Blume election approaches. Fearful that her true feelings for Hime have been discovered, Kanoko becomes suspicious of Sumika's motivations.
Kanoko's jealousy of Hime's closeness with Mitsuki begins to reach a breaking point, but Sumika moves to both help her and stand in her way.
Retreating from Sumika's confrontation, Kanoko reminisces about how she and Hime became friends.
Sumika reveals why she's determined to block Kanoko's romantic feelings toward Hime, but after Kanoko brushes her off, a conversation with another employee forces her to consider a different perspective on romance in the salon.
The Blume election results are in, and Sumika is determined to make things right with Kanoko.
The shift into summer means changes in Liebe Girls' Academy salon, but the new summer uniforms cause an unexpected problem with Mitsuki, and tea recommendations leave Hime outclassed. Luckily, her Onee-sama is there to save the day.
